Counter ions might be shown. Small deviations from ideal geometry may be due to crystal packing. See original references for the crystal structure.

Sandwich ComplexesDOICCDC code
A
FeCp2
doi.org/10.1107/S0108768197005132FEROCE27 131686
RuCp2 doi.org/10.1107/S0567740880010588CYCPRU07 1134586
FeCp2BF4 doi.org/10.1016/j.ica.2007.03.049AFALID 632409
FeCp(C6H6)AlBr4 doi.org/10.1016/j.ica.2007.03.049AFALEZ 632408
Ru(C6H6)CpPF6 doi.org/10.1039/a808278bBIBXUF01 1110148
B
Co(C4H4)Cp
doi.org/10.1016/S0022-328X(00)96130-8CBCPCO 1121368
CoCp2 doi.org/10.1007/BF00677370DCYPCO04 1137582
CoCp2Cl doi.org/10.1039/b205782dAHETIQ 188487
Co(C6H6)(C4Me4)PF6 Izvestiya Akademii Nauk SSSR,
Seriya Khimicheskaya (2014) 2290
BAFNEE 1005340
C
CrCp2
doi.org/10.1016/0022-328X(95)05747-DCYCPCR01 1134578
Cr(C6H6)2 doi.org/10.1016/S0022-328X(00)82388-8DBENCR03 1137243
Cr(C6H6)2Br Crystal Structure Communications (1981) 10, 1531BAWGEL 1106645
Cr(C6H6)(C10H8) doi.org/10.1016/0022-328X(85)88005-0CUWXUN 1134108 with added H
D
VCp2
doi.org/10.1107/S0108768195012213CPNDYV03 131565
VCp(C6H6) doi.org/10.1021/om0497442WADVON01 1289240
VCp(C7H7) doi.org/10.5517/cc5q0tpCPLHLV01 17012
KNbCp(C7H7) doi.org/10.1039/C39920000314KOSMEK 1199552
E
MnCp*2
doi.org/10.1021/ja00498a017DMCPMN 1142566
ReCp*2 doi.org/10.1021/ja00223a023GICFON 1167328
Re(C6H6)2BF4 doi.org/10.1016/j.jorganchem.2012.12.037PEVDEB 906764
MnCp(C7H7)PF6 doi.org/10.1021/acs.organomet.1c00376UYUROY 2079152
Tc(C6H6)2)PF6 doi.org/10.1039/C4SC02461CDOSQIN 1017765
F
Ti(C6H6)2
doi.org/10.1002/chem.201500737BELGOO11 1030722
TiCp(C7H7) doi.org/10.1016/S0022-328X(00)85010-XCPCHTI 1130909
TiCp(C8H8) doi.org/10.1016/S0022-328X(00)87847-XCPCOTI 1130946
NiCp2 doi.org/10.1107/S0567740880008539NCKLCN 1217918
G
KU(C7H7)2
doi.org/10.1039/c39950000183YIJKOR 1302984
U(C8H8)2 doi.org/10.1021/ic50111a034
doi.org/10.1021/ja01048a055
URACEN10 1278438
Nd(C8H8)(C9H9) doi.org/10.1038/s41467-019-10976-6UYOPTAB 1894447
KCe(C8H8)2 doi.org/10.1021/ic50118a031KECOCE10 1194083
H
Ni(C6H6)(PCy3)
doi.org/10.1039/C7CC08416AGEKZEE 1580329 without disorder
Ni(C4Ph4)(PEt3)2 doi.org/10.1515/znb-1985-0511DAJJON 1135678
Ni2Cp2(PPh2)2 doi.org/10.1021/ja00979a013PCPNID 1229479 with added H
Ti2Cp4(PMe2)2 Zeitschrift fur Naturforschung,
B:Chemical Sciences (1986) 41, 1535
FAGYUH 1151764 with added H
I
CoCp(CO)2
doi.org/10.1107/S0108270198002078NUTHEP 130319
Ir(C6H6)(PPh3)2PF6 doi.org/10.1021/acs.organomet.7b00676XERLIS 1572833
VCp(CO)4 doi.org/10.1002/cber.19881210903CPNPVC01 1131312 with added H
NbCp(C4Ph4)Cl2 doi.org/110.1021/om00035a036HASLOC 1172559
J
W(C7H7)I(CO)2
doi.org/10.1134/S1070328419050038GORLIL 1875096
Mo(C7H7)(CO)3BF4 doi.org/10.1016/S0022-328X(00)95105-2CYHMOC10 1134624
W(C7H7)(PPh3)2(CO)BF4 doi.org/10.1016/j.jorganchem.2006.01.013YEJXER 288657
Nb(C7H7)(PMe2CH2CH2PMe2)(CO) doi.org/10.1016/S0277-5387(00)80161-8KIZNAI 1198124
K
Cr(C6H6)(CO)3
doi.org/10.1021/ic50031a017BZCRCO 1118183
Mo(C6H6)(CO)3 doi.org/10.1107/S0108768191014404KUJLEG 1200864
WCp(CO)3Cl doi.org/10.1021/ic50221a051BACFAM 1104635
MnCp(CO)3 doi.org/10.1021/ic50223a023CPMNCO01 1131212
Fe(C4H4)(CO)3 doi.org/10.1021/ic00274a013FURROZ 1161541
L
FeCp(CO)3PF6
doi.org/10.1021/ic50126a008CPFEFP 1131060
RuCp(CO)2I doi.org/10.1107/S1600536806020186ADENAZ 613660
RuCp(OH2)3SO4 doi.org/10.1021/ic00281a009GAWTED 1164469
Ru(C6H6)(CO)H(PCy3)BF4 doi.org/10.1021/om100051hIKEKIT 810611
M
ReCp(C4Ph4)(CO)
doi.org/10.1016/S0022-328X(96)06705-8RIKJUQ 1250007
ReCp(C4Ph4)H2 doi.org/10.1039/a704076hRUPZAD 1253008
ReCp(C4Ph4)Br2 doi.org/10.1039/a704076hRUPYUW 1253007
RuCp(C4Ph4)(CH3CN)BF4 doi.org/10.1039/dt9870002803IMVID10 1125740
N
TiCp2(CO)2
doi.org/10.1016/S0022-328X(00)93722-7TITODC10 1271608
ZrCp2(CO)2 doi.org/10.1021/ic50214a044CCPZRA 1121627
TiCp2Cl2 doi.org/10.1139/v75-228CDCPTI01 1121676
TiCp2(OH2)2(NO3)2 doi.org/10.1002/zaac.19814760508AQCPTJ 1103453
HfCp(C7H7)(PMe3) doi.org/10.1016/j.jorganchem.2009.01.055 XOVGOF 713618
O
VCp2Cl
doi.org/10.1016/S0022-328X(00)80841-4 DCPVCL 1137543
MoCp2H2 doi.org/10.1021/ic50178a063HCYPMO02 1173408
ReCp*(CO)3Br+ doi.org/10.1016/S0277-5387(97)00500-7SUTRUU 106696
Nb(C7H7)(PMe2CH2CH2PMe2)(CO) doi.org/10.1016/S0277-5387(00)80161-8KIZNAI 1198124
P
YCp3
doi.org/10.1002/ejic.202000436SIXZEE01 1999525
Sc2Cp4Cl2 doi.org/10.1039/dt9730002487DCCPSC 1137398
Y2Cp4(C4H8O)2Cl2 doi.org/10.5517/cc9vq61MIRCOG 293793
Fe4Cp4(CO)4 doi.org/10.1021/ja00765a021CPFTEC 1131090
Q
U(C8H8)2(CN)
doi.org/10.1021/om800006uKOCMUL 688084.
UCp*2(CN)3-2 doi.org/10.1002/anie.200604114VEZXUU 622923
UCp*2(CN)5-2doi.org/10.1002/anie.200604114VEZYIJ 622926
UCp*2(acac)2 doi.org/10.5517/cc115s88ZIXHUL 958869
R
TiCp2(acac)
doi.org/10.1016/0020-1693(95)90052-8HIDPOZ 1176085
RuCp*(acac)(P(OMe)3) doi.org/10.1002/anie.199007731KEYXIV )1195880
cis-Fe2Cp2(CO)4 doi.org/10.1039/j19700003068CPFECO10 1131057
trans-Fe2Cp2(CO)4 doi.org/10.1021/ja00765a021CPFTEC 1131090
Rh(C6H6)(PPh2CH2CH2PPh2)BF4 doi.org/10.1002/chem.201201587DEJTIX 734951
S
FeCp(CN)(CO)2
doi.org/10.1021/ic010683zACODUR 176495
KFeCp(CO)2 Zeitschrift fur Naturforschung,
B:Chemical Sciences (1991) 46, 621
TAJXUX 1265783
KFeCp(CN)2(PPh3) doi.org/10.1002/ejic.200300304AVETUQ 211280
K2FeCp(CN)3) doi.org/10.1016/j.ica.2005.06.027KATYOU 267184
T
KFeCp*(CN)2(CO)
doi.org/10.1021/ja982053aHEQFEO 1174727
CoCp(CN)2(PPh3) doi.org/10.1016/j.ica.2003.11.016AWOQIM 222678
KCoCp(CN)3 doi.org/10.1016/j.ica.2003.11.016YEQGIK01 222676
(PhNH3)CoCp(CN)3 doi.org/10.1002/ejic.200700001CIGTUI 632475
U
Ru2(C6H6)2Cl4
doi.org/10.1016/j.molstruc.2014.03.046CICCOH01 988700
Ru(C6H6)Br3Re(CO)3 doi.org/10.1039/b004262pWOGLIN 150602
Co4(C6H6)(CO)9 doi.org/10.1016/S0022-328X(00)80386-1BNZCTC 1112718
CoCp(C4Ph4)Cr4(CO)12 doi.org/10.1016/0022-328X(94)87104-3YEPPAK 1301445
V
Mo(C7H7)(CO)2MoCp(CO)3
doi.org/10.1107/S0108270188009643JACFOI 1181531
Mo(C7H7)(CO)2RuCp(CO)2 doi.org/10.1016/0022-328X(91)86413-KKOPBIA 1199320
Mo2(C7H6-C7H6)I(CO)4PF6 doi.org/10.1039/dt9950003231ZEWNOE 1311688
Mo3Cp3(CO)6(P=O) doi.org/10.1039/a606262hTUCFAY 121832
W
Mo3Cp3(CO)6As
doi.org/10.1002/cber.19881210122CUXJOU10 1134154 with added H
Ni3Cp*3(CO)3Sb Zeitschrift fur Anorganische und
Allgemeine Chemie (2000) 626, 444
LIRMUU 134632
Ni3Cp*3As5 doi.org/10.1002/cber.19901230310VELSOU 1281902 with added H
Co4Cp4P4 doi.org/10.1021/ja00788a015CPCOPT 1130940
X
RuCp*RhCp*(C6H6)Cl3
doi.org/10.1002/ejic.200500692JECVET 279179
Ru(C6H6)2[Ru(C6H6)Cl3]2 doi.org/10.5517/cc14k810KUGCEW 1059271
Cr2Cp2(CO)4H(PMe2) doi.org/10.1021/om0203680WUMJIX 173120
Fe(C5H4PPh2)2Pt(P(CH3)2OH)(CF3SO3)2 doi.org/10.1021/acscatal.1c02254ADIBAU 2052650
Cp = η5-C5H5, Cp* = η5-C5(CH3)5, py = C5H5N, Ph = -C6H5, Cy = -C6H11,
Me = -CH3, Et = -CH2CH3, iPr = -CH(CH3)2, tBu = -C(CH3)3,
acac = CH3COCHCOCH3

This page created by George Lisensky, Beloit College. Last modified March 1, 2023.

References:

Back