Counter ions not shown. Small deviations from ideal geometry may be due to crystal packing. See original references for the crystal structure.

CO ComplexDOICCDC code
chromium(0)doi.org/10.1107/S0567740875008394FOHCOU01 1158524
molybdenum(0)doi.org/10.5517/cc6f4sjFUBYIK01 191387
tungsten(0)doi.org/10.5517/cc44xgmKOVSOD01 123890
manganese(I)doi.org/10.1021/ic700798zTINFAY 644834
technetium(I)doi.org/10.1107/S1600536808025208BOFQUJ01 675277
rhenium(I)doi.org/10.1039/dt9780001627FUZJOZ 1162205
iron(II)doi.org/10.1021/ic0482483CEHHON 232217
ruthenium(II)doi.org/10.1021/ic040115uLARPAW 281080
osmium(II)doi.org/10.1021/ic0482483CEHHIH 2322167
vanadium(-I)doi.org/10.1007/BF01667030TIRQAM 271400
niobium(-I)doi.org/10.1021/ic00155a009BILNEP10 1111024
tantalum(-I)doi.org/10.1021/ic00155a009BUVGII 1117448
titanium(-II)doi.org/10.1021/ja00172a017SIDGIV 1258653
zirconium(-II)doi.org/10.1021/ja00172a017SIDGOB 1258654
hafnium(-II)doi.org/10.1021/ja00172a017SIDGUH 1258655
iron(0)doi.org/10.1107/S0365110X62003771FOJBOV 1158628
ruthenium(0)doi.org/10.5517/cc783l5FOKNEY06 216336
osmium(0)doi.org/10.1021/ic50170a032FOKBUC01 1158742
Fe2(CO)9doi.org/10.1039/dt9740000800FUZGAI 1162195
Fe3(CO)12doi.org/10.1021/ja00820a016GAFMEF01 1162674 one-half
manganese(-I)doi.org/10.1016/S0022-328X(00)90652-1FUDKAQ 1160544
rhenium(-I)doi.org/10.1021/ic2003035EZILOP 812642
chromium(-II)doi.org/10.1039/D1CP01592CISAXEG01 2059985
molybdenum(-II)doi.org/10.1039/D1CP01592CAZUQOE 2059986
tungsten(-II)doi.org/10.1021/om00127a009
cobalt(I)doi.org/10.1002/anie.200250780UJISEL 199269
rhodium(I)doi.org/10.1021/ja993628mGONLAW 1170018
palladium(II)doi.org/10.1021/ja002360sQEZTAQ 160077
platinum(II)doi.org/10.1021/ja002360sQEZTEU 160078
nickel(0)doi.org/10.1021/om00028a082FOJBUB02 1158633
cobalt(-I)doi.org/10.1021/om0340701BEHVOA 226591
iron(-II)doi.org/10.1021/ja00446a022NCRYFE 1217933
copper(I)doi.org/10.1021/ic990321fMEBNIQ 1210594
manganese(0)doi.org/10.1107/S0567740882001939FOJCEM01 1158636
technetium(0)doi.org/10.1134/S1066362211010061FOKCIR01 1055457
rhenium(0)doi.org/10.1021/ic50219a056FUZTOJ 1162244
chromium(-I)doi.org/10.1107/S0108270195001454HIFFEH 126339
molybdenum(-I)doi.org/10.5517/cc59b70QOVDAG 157921
tungsten(-I)doi.org/10.1039/D0DT01921FSUSSIL 1953958
cobalt(0)doi.org/10.1107/S0365110X64001803 FOHDEL 1158529
rhodium(0)doi.org/10.1021/ic50081a030 FOWTIU 1159842
iridium(0)doi.org/10.1021/ic50190a040FOJVEF 1158714
cobalt(0) occasionallydoi.org/10.1039/b915083hYUGWUT 737632
Co4(CO)12doi.org/10.1016/S0022-328X(98)00879-1FOWTEQ02 122744
iron(-I)doi.org/10.1016/j.jorganchem.2012.07.040SENCAR 884879
ruthenium(-I)doi.org/10.1021/om00127a041QANJOI 2115042
osmium(-I)doi.org/10.1021/om00127a041DELHOR 1138573
titanium(0)doi.org/10.1002/chem.201905552
vanadium(I)doi.org/10.1016/j.cplett.2008.03.017
niobium(I)doi.org/10.1038/s41557-020-0487-3XUTBOG 1909275
tantalum(I)doi.org/10.1038/s41557-020-0487-3XUTCAT 1909276
tantalum(0)doi.org/10.1038/s41557-020-0487-3XUTBIA 1909274
nickel(-II)doi.org/10.1002/zaac.201800111ZIYKAW 1526303
platinum(-II)doi.org/10.1002/zaac.202100378ADEGUP 2103387

Some electron counting problems
A
Mn(CO)5Cl
doi.org/10.1039/j19710001559ZOSWEJ 1315279
Re(CO)5Cldoi.org/10.1107/S0108270183009014FOHCAG 1158516
Cr(CO)5I-doi.org/10.1007/s11243-005-1018-1NATZIS 251204
W(CO)5I-doi.org/10.1039/a700215gRAGJEO 1246320
W(CO)5pydoi.org/10.5517/cc3sk8pFACPII01 112972 with added H
W(CO)5(PH3)doi.org/10.1021/om020311dXIBVUZ01 190775
B
Mo(CO)4I3
doi.org/10.1039/dt9860002569FEYKOJ 1155481
W(CO)4I3doi.org/10.1002/anie.200602617CEZFAP 606431
Mo(CO)3I2(MeCN)2doi.org/10.1023/A:1006985429084HORKUU 103352
W(CO)3I2(MeCN)2doi.org/10.1016/S0277-5387(00)80560-4GIFGAD 1167544
Mn(CO)5Hdoi.org/10.1021/ic50079a025FOKCEN02 1158747
Cr(CO)5Hdoi.org/10.1021/ja00389a013BOSKOJ 1114173
C
cis-Fe(CO)4I2
doi.org/10.5517/ccr5232CUCQIB 690063
trans-Cr(CO)4(PPh3)2doi.org/10.1016/S0022-328X(01)00929-9OCUHID 163156
fac-Fe(CO)3I3doi.org/10.1016/j.inoche.2009.04.006GUHZUF 743307
mer-Re(CO)3H(PPh3)2Zeitschrift fuer Kristallographie
Crystalline Materials (1992) 202, 317
PARFIX 1228290
D
Fe(CO)4(PPh3)
doi.org/10.1021/ic50203a033PPTCFE 1237877
Fe(CO)3(PPh3)2doi.org/10.5517/cc9g9lmLETLEC 281870
Cr(CO)4(PMe2CH2CH2PMe2)doi.org/10.1524/zkri.1994.209.1.77PINVAJ 1234099
Ru(CO)3H(PtBu2CH2CH2PtBu2)+doi.org/10.1039/b415812aFIGZOL 250932
E
Mn2(CO)8Br2
doi.org/10.1107/S1600536806005885FOHDIP01 1431757
Re2(CO)8I2doi.org/10.1016/S0022-328X(00)93314-XFOLHOD 1158870
Nb2(CO)8Cl3doi.org/10.1039/C39820001304BIXDIV 1112095
Nb2(CO)8I3doi.org/10.1002/cber.19921250505VUDYEY 1287394
W2(CO)8Cl3+doi.org/10.1039/C9SC06445ALUMQES 1952387
W2(CO)8Br4doi.org/10.1016/10.1021/ic00198a017FURYOG 1161575
F
Os2(CO)8I2
doi.org/10.1016/S0020-1693(00)83380-0GEHDOM 1165426
Re2(CO)8(PPh3)2doi.org/10.1021/om4010127GIYQOW 984973
Mo2(CO)8I2doi.org/10.1107/S0567740876003452FOPHUN 1159215
W2(CO)8(PPh2)2doi.org/10.1021/ja00246a018DIMHIQ10 1141116
G
Mn3(CO)14
doi.org/10.5517/ccdc.csd.cc2c2xw8YAZDOW 2177560
FeRe2(CO)14doi.org/10.1107/S0108270190011258GIPSON01 1168398
Re2Pt(CO)12doi.org/10.1021/ic00187a011FUZWIG 1162254
Os3(CO)12I2doi.org/10.1007/s10876-012-0532-5FUZHEN01 896125
H
Ru3(CO)10(PPh2CH2CH2PPh2)
doi.org/10.1016/S0022-328X(02)01567-XCUSHAZ01 177736
Ru2(CO)8Pt(PPh2CH2CH2PPh2)doi.org/10.1007/BF00702713LAWCUH 1204020
Fe2Co2(CO)11(PPh)2doi.org/10.1002/cber.19831160333BADWOS10 1104911
Co3(CO)6(PPh2)3 doi.org/10.5517/cc46rz1QAFZUS 125673
I
Fe4(CO)16Pb
doi.org/10.1021/ic00268a017FORYEQ 1159437
Fe4(CO)16Sndoi.org/10.1039/j19670000382VEPFEC 607539
Fe4(CO)16Gedoi.org/10.1016/S0022-328X(00)99431-2PEQNEE02 607538 with fixed O3A
Fe4(CO)13–2doi.org/10.1039/b703628kCIFXAR 639853
Re6(CO)18(PMe)3doi.org/10.1039/C39850000478CUSVIV 1133765 with added H
Ni8(CO)8(PPh)6doi.org/10.1021/ja00432a072CONPOS 1129493
J
Mn4(CO)12Br4(pz)4
doi.org/10.1021/om201244aBEJPAJ 851351
Re4(CO)12Br4(pz)4doi.org/10.1039/b101992iUDAVOK 160973
Os4(CO)16doi.org/10.1021/om00160a024GABTUY10 1162367
Os4(CO)15(PF3)doi.org/10.1021/om00160a024VIBLEX 1283210
Tc4(CO)12Cl4Radiokhimiya (1994) 36, 199POSLOY10 1237191
Re4(CO)12F410.1071/CH9810737FOVPIP 1159717
K
Co66-C)(CO)15–2
doi.org/10.1039/dt9850000035CUZNOA 1134380
Rh66-C)(CO)15–2doi.org/10.1039/dt9730000651CBRHAM10 1121478
Fe55-C)(CO)15doi.org/10.1021/ja00883a004FUZBAD 1162174
Ru55-C)(CO)15doi.org/10.1039/c39810000415CAQQEQ 135027
Os55-C)(CO)15doi.org/10.1039/c39800000564CAQQOA 135024
Re44-C)(CO)15Idoi.org/10.1039/c39850000978DAJBIZ 1135646
Pd33-CO)(μ-PPh2CH2PPh2)3+2doi.org/10.1039/C39830001336CASMUE 1120566 with added H
L
MnFe(CO)8(PH2)
doi.org/10.1021/om100736mOMASOL 815724
W2(CO)10Sn(py)2European Journal of Inorganic Chemistry (1998) 703POZCEM 1237702
Fe3(CO)12(AsH)-2doi.org/10.1021/om00002a029WICHUL01 1293153
Mn3(CO)13Br(PH)doi.org/10.1107/S0108270197000735REMREG 128833
M
Co22-CO)25-C5H5)2
New Journal of Chemistry (1988) 12, 621GOBYEB 1169493
Cr22-CO)36-C6H6)doi.org/10.1002/cber.19851180509DEHMEI 1138251 with added H
Co33-CO)26-C6H6)3+doi.org/10.1021/ja00284a033FAGPAE 1151715
Fe43-CO)45-C5H5)4doi.org/10.1021/ja00765a021CPFTEC 1131090
Me = -CH3, Ph = -C6H5, tBu = -C(CH3)3, py = C5H5N, pz = NC4H4N

This page created by George Lisensky, Beloit College. Last modified February 6, 2023.

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