Counter ions not shown. Small deviations from ideal geometry may be due to crystal packing. See original references for the crystal structure.

Nitrogen ComplexesDOICCDC code
A
trans-V=O(cyclam)Cl+		doi.org/10.1021/ic9020614WAJGAR 748341
trans-Cr(cyclam)(H2O)(OH)+2 doi.org/10.1107/S0108270195012996 ZUZSOC 126723
cis-Cr(cyclam)Cl2+doi.org/10.1107/S0108270186095392DOHBEH 1143552
trans-Cr(cyclam)Cl2+doi.org/10.1039/b405789a
doi.org/10.1016/j.ica.2004.06.050		ABILUT 195378
cis-Cr(cyclam)(C2O4)+doi.org/10.1016/j.molstruc.2004.01.034IHAFOM 196029
B
Co(cyclam)+		doi.org/10.1021/ja00444a020COANEC 1128009 with added H
Ni(cyclam)+2doi.org/10.1039/b408085hMAFRIV 240052
Pd(cyclam)+2doi.org/10.5517/cc9938yQASKIF 276869
Cu(cyclam)+2Koordinatsionnaia khimiia (1992) 18, 474HAFSUC 1171378
Au(cyclam)+3doi.org/10.1080/00958979308035142POPKUA 1236872 with added H
C
trans-Mn(cyclam)Cl2		doi.org/10.1107/S0108270195016829TEGPUQ 127080 without disorder
trans-Ru(cyclam)Cl2+doi.org/10.1021/ic50223a019BANRAJ 1105966
trans-Mn(cyclam)Cl2+doi.org/10.1039/a800824hGEQMIY 1166174
trans-Zn(cyclam)(H2O)2+2doi.org/10.1002/chem.200304808ALOJIU 202455
D
cis-Mn(cyclam)(CO)2+		doi.org/10.1246/cl.170869NEMPAZ 1572764
trans-Co(cyclam)Cl2+doi.org/10.1107/S1600536806021830ADEFIZ 613591
cis-Rh(cyclam)Cl2+doi.org/10.1080/00958978708079806FUFJAR 1160634
cis-Ni(cyclam)(H2O)2+2doi.org/10.1021/ic00243a028FAGVUE 1151747
trans-Pd(cyclam)Cl2+2doi.org/10.1021/ic00152a032BUXSOC 1117720
trans-Pt(cyclam)Cl2+2doi.org/10.1021/ic00019a025SONNEO 1261986
E
trans-Tc(=O)2(cyclam)+		doi.org/10.1021/ic50222a006BAPPIR 1106074
trans-Fe(cyclam)Cl(NO)+doi.org/10.1021/ja994161iLOJJEZ 145762
trans-Rh(cyclam)ClH+doi.org/10.1021/ic960300aNAKYON 1216342
trans-Ru(cyclam)Cl(NO)+2doi.org/10.1021/ic9912979LOLKIG 112418 with added H
F
trans-Ni(cyclam)(H2O)2+2		doi.org/10.1021/ic00129a006ZIQXOM 1313027
trans-Ni(cyclam)Cl2doi.org/10.1246/bcsj.57.2641TAZDNC01 1267358
trans-Ni(cyclam)(MeCN)2+2doi.org/10.1039/b408085hMAFRER 240051
trans-Cu(cyclam)(H2O)2+2doi.org/10.1080/00958970310001624302IPEYUX 188537
G
fac-Ti(MeCN)3Cl3+		doi.org/10.1039/c39870001100FIKXIG 1156494
fac-Ti(MeCN)3F3+doi.org/10.1039/b500993fDAVLUI 250627
mer-Ti(py)3Br3Koordinatsionnaia khimiia (1990) 16, 466VIXCAG 1284987
mer-Ti(py)3Cl3Koordinatsionnaia khimiia (1995) 21, 332SITHAE01 1260077
mer-V(py)3Cl3doi.org/10.1107/S0108270193005268WEHZUE 1291588
mer-Ta(py)3Cl3doi.org/10.1016/0020-1693(95)04779-4NAFRUH 1215926
mer-V(bipy)(MeCN)Cl3doi.org/10.1039/b911586bQUNKEQ 736080
H
mer-Cr(py)3Cl3		doi.org/10.1007/BF01164777QQQFYV01 1245158
mer-Mo(py)3Br3doi.org/10.1002/zaac.201300122ZZZBTJ02 919279
mer-Mo(py)3Cl3doi.org/10.1002/zaac.19744030218CLPYMO10 1127402 with added H
mer-Mo(Mepy)3Br3doi.org/10.1107/S0567740880004189ZZZCCA10 1318203
fac-Mo(MeCN)3Cl3doi.org/10.5517/ccdc.csd.cc13swj9KOLDUN 1036811 without disorder
mer-Mo(MeCN)3I3doi.org/10.1023/A:1006985429084HORLAB 103353
mer-Mn(py)3F3doi.org/10.1039/C5DT01748CYUKQAY 1063082
mer-Re(py)3Br3doi.org/10.1002/zaac.19966220203ZOKLIU 1314512
fac-Re(py)3Cl3doi.org/10.5517/cc89xr6PAHNAO 247868
Zn(py)Cl3–doi.org/10.1107/S160053681402145XBOMSUT 1026562
I
fac-Tc(Mepy)3Cl3		doi.org/10.1021/ic00343a040JEVMAY 1185228 with aded H
mer-Ru(MeCN)3Cl3doi.org/10.1016/S0022-328X(99)00532-XMAWFEV 131450
mer-Fe(py)3Cl3doi.org/10.1107/S0108270183007295CAFNIG 1119052
mer-Os(py)3Cl3doi.org/10.1107/S0108270188006870VUXMAC 1288742
mer-Os(py)3Br3Zeitschrift fur Anorganische und Allgemeine Chemie (1999) 625, 43GOBBUU 105962
mer-Os(py)3I3Zeitschrift fur Anorganische und Allgemeine Chemie (1999) 625, 43GOBCAB 105963
mer-Ru(bipy)(MeCN)Cl3doi.org/10.1021/ic990840iDOKVEE 142214
fac-Ir(phen)(MeCN)Cl3doi.org/10.1002/cmdc.200800311BONQUR 701113
J
mer-Co(dien)Cl3		doi.org/10.1021/cg000003nQIGRON 161281
mer-Ir(en)(py)3Cl3Zhurnal Neorganicheskoi Khimii (2004) 49, 587IBEFUR 1179272
fac-Ir(MeCN)3Br3doi.org/10.1016/j.inoche.2015.07.013ZUMTAE 1401625
mer-Rh(MeCN)3Cl3doi.org/10.1016/0020-1693(95)04585-6TIWWIF 1271819 with added H
K
mer-Rh(py)2(MeCN)Cl3		doi.org/10.22075/CHEM.2019.15485.1490HOXLAK 1848809
mer-Rh(py)3Cl3doi.org/10.1107/S0108270184007848CILYOL 1125647 with modified H
Cu(py)4+2doi.org/10.1524/ncrs.2011.0085ISAFIS 832725
Cu(py)4+doi.org/10.1107/S1600536807024051GIGXOK 651160
L
fac-Pt(dien)Cl3+		doi.org/10.1107/S0567740880010618ENTAPT 1149824 with added H
mer-Pt(en)(py)Cl3Zhurnal Neorganicheskoi Khimii (2001) 46, 1279FADNOO 1151480 with added H
mer-Pt(en)(py)Cl3+Zhurnal Neorganicheskoi Khimii (2006) 51, 1994JOCYOQ 1188009
mer-Pt(en)(py)Br3+Zhurnal Neorganicheskoi Khimii (2006) 51, 1266CIKGAF 1125434
mer-Au(dien)Cl3doi.org/10.1021/ic00222a026DODXID 1143340
M
trans-V(py)4Cl2		doi.org/10.1038/s41467-022-33342-5TPYCLV02 2158354
trans-Nb(py)4Cl2doi.org/10.1021/ic00126a009ZIDQIM01 1312189 with modified H
trans-Cr(py)4F2+doi.org/10.1021/ic00024a041KOMREJ 1199186
cis-Mn(bipy)2Cl2doi.org/10.1107/S1600536806020332ADEVIP 613694
cis-Fe(bipy)2Cl2+doi.org/10.1107/S0108768183003286CAVDOS 1120815
N
trans-Ru(py)4Cl2		doi.org/10.1107/S0108270194002088WIBNIE 1293079
cis-Co(bipy)2Cl2+doi.org/10.1515/ncrs-2000-0415QQQEQG01 137678
trans-Co(py)4Cl2+doi.org/10.1002/chir.530010407SICWEG 1258604
trans-Rh(py)4Cl2+doi.org/10.1134/S0022476615020158GAKJOU 812098
trans-Pt(py)4F2+2doi.org/10.1002/zaac.19976230180TULKAM 1276728
O
cis-Ni(bipy)2Cl2		doi.org/10.1016/S0277-5387(98)00128-4CEFHIE 1122265
trans-Ni(py)4Cl2doi.org/10.1107/S1600536804033586FERQUP 262292
trans-Ni(py)4(H2O)2+2doi.org/10.1016/S0020-1693(02)01322-1RUZBOD 208341
trans-Cu(py)4Cl2doi.org/10.1039/b309842gOMIROR 217696
P
cis-Cr(en)2Cl2+		doi.org/10.5517/ccppljgEGULOI 646366
trans-Cr(en)2Cl2+doi.org/10.1246/bcsj.33.354CEDCRC 1122123 with added H
cis-Co(en)2Cl2+doi.org/10.1007/BF00622132CLECOC 1127122 with added H
trans-Co(en)2Cl2+Crystal Structure Communications (1981) 10, 239EDCHCO 1148601
cis-Rh(en)2Cl2+Zhurnal Strukturnoi Khimii (1979) 20, 1096CENRHA 1123128 with modified H
trans-Rh(en)2Cl2+Zhurnal Strukturnoi Khimii (1979) 20, 1096CENRHB 1123129
trans-Pt(en)2Cl2+2doi.org/10.1107/S0108270190000567JESGAP 1185011
trans-Ni(en)2Br2+doi.org/10.1021/ic00055a025SUGSUI 1263872
Q
Ni(en)2+2		doi.org/10.1107/S1600536804032052FAXLUM 262247
Pd(en)2+2doi.org/10.1021/ic50044a029PDCLED 1229568
Pt(en)2+2doi.org/10.5517/cc1jz90tZZZEDM03 1429286
Au(en)2+3Zhurnal Neorganicheskoi Khimii (1988) 33, 683JIHGOW 1186197
Cu(en)2+2doi.org/10.1107/S0108270101020789DADTOR01 181987
Cr(py)4+2doi.org/10.1021/ic00024a041KOMRAF 1199185
R
trans-Cr(en)2(NH3)F+2		doi.org/10.1107/S0108270185005923DAFHOH 1135330
trans-Os(en)2(py)H+2doi.org/10.1021/ic030091bTAFRIC 214021
Co(en)2(bipy)+3doi.org/10.1071/CH99060XAPTEN 1295353 with modified H
cis-Co(en)2(NH3)Cl+2doi.org/10.1071/CH9860339DOCZOK 1143249
cis-Co(en)2(NH3)Br+2European Journal of Inorganic Chemistry (2000) 189CULQUV 118585
S
cis-Co(en)2(py)Cl+2		doi.org/10.1021/ic00023a017JOGRAY 1188273
cis-Co(en)2(py)Br+2doi.org/10.3891/acta.chem.scand.23-3274aBPYCOE 1115145 with added H
cis-Ni(en)2(H2O)2+2doi.org/10.1107/S1600536803028988IROPEK 231838
trans-Ni(en)2(H2O)2+2doi.org/10.1002/zaac.200500235 NAXVAK 261635
cis-Ni(en)2(py)2+2doi.org/10.1107/S0108270199010458BOMQID 138075
cis-Ni(en)2(H2O)I+Zhurnal Strukturnoi Khimii (1972) 13, 81IENANI 1179726 with added H
T
Cu(en)2Cl+		doi.org/10.5517/cc5p678GAPZIH 169329
Cu(en)2(H2O)+2doi.org/10.1016/S0020-1693(00)00173-0WODCEX 139022
trans-Cu(en)2(H2O)2+2doi.org/10.1134/S002247661911012XGABQOT 1901168
cis-Cu(bipy)2I2doi.org/10.1107/S1600536806015893ADEBIV 610863
U
V(en)3+2		doi.org/10.1016/0020-1693(94)04222-HHIDMEM 1176075
Cr(en)3+3doi.org/10.1107/S0567740878004082CRENCL01 1131647
Mn(en)3+2doi.org/10.1107/S2053229617006738YANKOQ 1547933
Fe(en)3+2doi.org/10.1107/S2053229617006738YANKUW 1547934
Ru(en)3+2doi.org/10.1021/ic50221a052BABRAX 1104534
Co(en)3+3doi.org/10.1107/S2056989021009336VAFJUL 2042981
Rh(en)3+3doi.org/10.1039/b806467aXOHYUP 697680
V
Co(en)3+2		doi.org/10.1107/S1600536813013135IDULOK 954384
Ni(en)3+2doi.org/10.1107/S2053229617006738YANLEH 1547936
Cu(en)3+2doi.org/10.1107/S2053229617006738TAQMAA01 1547937
Zn(en)3+2doi.org/10.1107/S2053229617006738YANLOR 1547938
Cd(en)3+2doi.org/10.1107/S160053681200983XYATRIW 877049
W
trans-Cr(PMe2CH2CH2PMe2)2(N2)2		doi.org/10.1021/ja00356a060CAMVOB 1120061
trans-Mo(PEt2CH2CH2PEt2)2(N2)2doi.org/10.1002/ejic.200500721SECROI 280785
trans-W(PEt2CH2CH2PEt2)2(N2)2doi.org/10.1021/acs.inorgchem.0c03271ONIDUN 2036361
trans-Mo(PPh2CH2CH2PPh2)2(N2)2doi.org/10.1107/S0567740875004803NDPEMO10 1217969
trans-W(PPh2CH2CH2PPh2)2(N2)2doi.org/10.1021/ic9508280ZURKIG 1316948
trans-Mn(PMe2CH2CH2PMe2)2H(N2)doi.org/10.1021/om00059a027YAJTIM 1298948
trans-Tc(PPh2CH2CH2PPh2)2H(N2)doi.org/10.1002/zaac.19824940111BOJLIV 1113337
Re(PPh2CH2CH2PPh2)(PPh3)Cl2(N2)–doi.org/10.1021/acs.organomet.0c00049AHEWES 1973407 without disorder
Re(PPh3)2(CO)2Cl(N2)doi.org/10.1016/j.jorganchem.2006.06.015HEPVUU 601690
X
trans-Fe(PEt2CH2CH2PEt2)2Cl(N2)+		Angewandte Chemie, International Edition (1998) 37, 815NIYJEK 1221249
trans-Fe(PEt2CH2CH2PEt2)2H(N2)+doi.org/10.1021/jacs.6b08802YAHKIE 1500137
Fe(PCy2CH2CH2PPhCH2CH2PCy2)H2(N2)doi.org/10.1039/C8CC07466FAFUXEH 1812144
Ru(PCy3)2H2(N2)2doi.org/10.1021/acs.organomet.7b00632YECMIF 1530724
Y
trans-Re(PMe3)4Br(N2)		doi.org/10.5517/ccdc.csd.cc1psbg8QEFCOW 1572520 without disorder
Mo(PMe3)5(N2)doi.org/10.1039/dt9950003801BIWGAP10 1111972 with added H
cis-Mo(PMe3)4(N2)2doi.org/10.1021/ja00348a014BUSZEU 1117275 with added H
trans-W(PMe3)4(N2)2doi.org/10.1016/S0277-5387(00)83957-1BUYBUS 1117756 without disorder
cis-Mo[(PPh2CH2CH2PPhCH2)2CH2](N2)2doi.org/10.1039/c0dt01646bAQUVOY 803783
Z
W2(PMe3)4Cl6(μ-N2)		doi.org/10.1016/j.ica.2009.08.025EKEWAT 731837
W2(PMe3)6Cl4(μ-N2)doi.org/10.1016/j.ica.2009.08.025EKEVUM 731836
Ni2(PiPr3)4(μ-N2)doi.org/10.1039/c2dt32008hLEKXEG 896753
Ru2(PiPr3)4H4(μ-N2)doi.org/10.1021/om990669iQINXUG 1243065
Me = -CH3, iPr = -CH(CH3)2, tBu = -C(CH3)3, Ph = -C6H5, Cy = -C6H11,
cyclam = , py = C5H5N, bipy = ,
en = NH2CH2CH2NH2, dien = NH2CH2CH2NHCH2CH2NH2
This page created by George Lisensky, Beloit College. Last modified February 16, 2023.

References:

Back