Counter ions might be shown. Small deviations from ideal geometry may be due to crystal packing. See original references for the crystal structure.

Sandwich Complexes (2)DOICCDC code
A
TaCp*(C7H7)(CH3)
doi.org/10.1021/ic8015035NOKZUJ 713017
Fe(η5-C5H5)(η1-C5H5)(CO)2doi.org/10.1021/acs.organomet.5b00661CPICCP01 1429917
NiCpPh(PPh3) doi.org/10.1039/j19690000266CPPPNI10 1131374
W(C7H7)(CF3)(CO)2 doi.org/10.1016/j.poly.2022.115875KAZSUD 2076889
B
Ru(C6H6)PhCl(PPh3)
doi.org/10.1080/00945719809349378XAWPOA 1295560
Os(C6H6)(C11H8N)Cl doi.org/10.1021/ic0346578BEDYUF 223818
CoCp(C8H8) doi.org/10.1016/0022-328X(92)85028-UPAMYAD 1227838
MnCp(Ph2C)(CO)2 doi.org/10.1021/ic00187a016COZYEV 1130805
C
MoCp*(PMe3)(CH3)2(NO)
doi.org/10.1021/ja002856+XISFUA 1296954
MoCp(PPh3)Br(CH3)(NO) doi.org/10.1039/dt9880000819GAGJIH 1162789
MoCp(CH3CN)2Cl(NO)+ doi.org/10.1021/om00038a062KOWNIT 1199848
MoCp*(CH3CN)3(NO)+2 doi.org/10.1021/om00038a062KOWNEP 1199847
D
TcCp(PPh3)Br(NO)
doi.org/10.1039/C6CC05811FERARAS 1491441
TcCp(PPh3)Ph(NO) doi.org/10.1039/C6CC05811FERARIA 1491443.
TcCp(PPh3)(CO)(NO)+ doi.org/10.1039/C6CC05811FERAREW 1491442
TcCp(PPh3)2(NO)+ doi.org/10.1002/ejic.202100521UBUXUO 2083773
E
ReCp(PiPr3)(CH3)(NO)
doi.org/10.5517/cc3jr1dSOWFIT 105463
ReCp(CO)(CH3)(NO) doi.org/10.1002/anie.201406071ROZZEN 1002240
ReCp(CO)(PPh3)(NO)+ Bulletin de la Societe Chimique
de France (1997) 134, 793
PARGAQ 1228293
ReCp(PPh3)(NH3)(NO)PF6 doi.org/10.1021/om970792ePATJAV 100852
F
ReCp*H(CH2CHCH2)
doi.org/10.1021/ja00191a074SASMAA 1255268
ReCp*(CO)2(CH2CHCH2)BF4 doi.org/10.1016/0022-328X(90)85315-PSIMHAX 1259458
WCp(CH2CHCH2)I(NO) doi.org/10.1021/ic50201a064CNALWI 1127852
IrCp*(CH2=CH2)(CH2CHCH2)(CF3SO3) doi.org/10.1021/om00159a008SIFROO 1258817
G
CrCpCl(NO)2
doi.org/10.1107/S0567740880004554CPNCRC01 1131286
Co(C5H4CH3)(NO) doi.org/10.1021/ja00336a027CUCFUB 1132201
MoCp*(PPh2CH2CH2PPh2)(NO) doi.org/10.1021/acs.inorgchem.7b00027YAXJOZ 1501176
Ni(C6H3(CH3)3)(NO)+ doi.org/10.1021/ic201821tRAQLEC 863272
H
WCpPh(CO)3
Zhurnal Strukturnoi Khimii (1968) 9, 1046CPCAPW10 1130888
ReCp*Ph(CO)2I doi.org/10.1016/S0022-328X(96)06767-8NIRBIZ 1220668 with added H
Fe(C5Ph5)Ph(CO)2 doi.org/10.1107/S2053229621006057AWAGAJ 2089240
IrCp*Ph2(CO) doi.org/10.1016/j.jorganchem.2013.03.014XEXYIK 893379
I
Cr(C5H2tBu3)(CH3)(CO)3
doi.org/10.1002/ejic.201900275NONTES 1915127
MoCp*(tBuCH2)2(NO) doi.org/10.1021/ja0349094UJAHAO 213553
MoCp*(tBuCH2)Ph(NO) doi.org/10.1021/ja0349094UJAHIW 213555
NiCp*(CH2=CH2)Ph doi.org/10.1002/cber.19881211109VAHZAF 1279319
J
ReCp(PhCH)(CO)2
doi.org/10.1021/om00028a041JUZSEC 1191756 with added H
Re(PhCH)(NO)(PPh3)PF6 doi.org/10.1021/ja00382a021BOBYAS 1112823
Cr(C6H6)(CPhOMe)(CO)2 doi.org/10.1016/S0022-328X(00)83509-3BCMPCR 1107253
FeCp(CO)(PPh3)(PhCO) Zhurnal Strukturnoi Khimii (1969) 10, 664FECPCB10 1153676
K
TaCp*(PhC)(PMe3)2Cl
doi.org/10.1021/ic50191a036TABYCP10 1265041 with added H
CrCp(PhC)(CO)2 doi.org/10.1016/S0022-328X(97)00084-3ROPSIY 1251945
ReCp*(PhC)(CO)2BCl4doi.org/10.1021/om010276vOFEZUU 1225748
OsCp(PhC)H(PiPr3)PF6 doi.org/10.1021/om0208826HACDIZ 205631
L
ReCp(CO)2Br(PhCO)
doi.org/10.1016/S0022-328X(96)06401-7RATYIU 1246963
RuCp(PPh3)(PhCCOPh)Cl doi.org/10.1021/ic00075a065CLCBCR06 1127075
MnCp(CO)2(PhCO)NMe4 doi.org/10.1107/S0567740871002899CPOCMN 1131318
RhCp(Ph2C)(CO) Chemistry-A European Journal (2000) 6, 4461QATQAD 146602
M
ReCp*(tBuC)Br3
doi.org/10.1021/om00119a013VESPOY 1282523
RuCp*(tBuCH2C)(PPh3)Cl+ doi.org/10.1021/om030559iERIYOT 1150112
MoCp(tBuCH2C)HP(OMe)3BF4 doi.org/10.1039/dt9890000511BENFEF10 1108634
MoCp(tBuCH2C)P(OMe)3((NC)2C=C(CN)2) doi.org/10.1039/dt9890000511KAJGUX 1192439 modified H
N
RuCp(Ph2C)(PPh3)Cl
doi.org/10.1016/S0022-328X(97)00045-4RIYCUX 1250853
RuCp(Ph2C)(CO)(PPh3)PF6 doi.org/10.1002/chem.200304740AQACOK 201502
MnCp(Me2C)(CO)2 doi.org/10.1016/S0022-328X(00)85481-9MCBCMN 1210087
CrCp(Ph2C)(NO)(CO) doi.org/10.1021/ic00187a016COZYAR 1130804
O
IrCp*(CH2=CH2)(NO)BF4
doi.org/10.1021/om00017a070PIXHIN 1234860
RhCp(CH2=CH2)(PPh3) doi.org/10.1021/om060500mXEPJIM 616691
RhCp(CH2=CH2)(CHPh=CHPh) doi.org/10.5517/cc5m0mdXISYON 167233
RuCp(CH2=CH2)(PiPr2CH2CH2PiPr2)BPh4 doi.org/10.1021/om9602116RACGOR 1246030
P
TiCp*2(PhC≡CPh)
doi.org/10.1016/j.inoche.2007.03.017DIHZAW 639280
TiCp2(CO)(PhC≡CPh) doi.org/10.1039/dt9780001398CBPATI 1121456
CoCp*(CH2=CH2)2 doi.org/10.1107/S2056989016012822ISUQUK 1498272
Rh(C9H7)(CH2=CH2)2 doi.org/10.1021/om00139a024DUMVUC 1146583
Ir(C9H7)(CH2=CH2)2 doi.org/10.1107/S1600536813025300 AGONER 960699
Q
Ni2Cp2(HC≡CH)
doi.org/10.1021/ic50159a029ACYPNI01 1101152 with added H
Co(C6H6)(CH3C≡CCH3) doi.org/10.1002/anie.198807061GESZOT 1166459
ReCp(PhC≡CPh)(CO)2 doi.org/10.1021/om00122a010CUKLAV 113302
W(C4Ph4)(PhC≡CPh)2(CO) doi.org/10.1021/ja00032a056SUBZUK 1263467
R
Ru2Cp*2(NO)2
doi.org/10.1016/j.poly.2007.04.009SILLEF01 633805
Os2Cp*2(NO)2 doi.org/10.1021/om980657hMEBSAN 1210615
Ru2Cp*2Cl2(NO)2 doi.org/10.1021/ja00024a024JOHNUP 1188365
Mo2Cp2Cl2(NO)2 doi.org/10.1107/S0108270194005755LEZBEX 1206434
Ir2Cp*2I3(NO) doi.org/10.1021/om00017a070PIXHOT 1234861
S
Rh2Cp*2(CO)(NO)+
doi.org/10.1039/dt9840001659COBGIJ 1128041
Mo2Cp2(PCy2)(NO)3 doi.org/10.1021/acs.inorgchem.5b02292DUXPIX 1429198
Mo2Cp2(PPh2)(NO)2(CO)2BF4 doi.org/10.5517/ccdc.csd.cc20p5rnKIKXOU 1867401
W2Cp2H4(NO)2 doi.org/10.1021/ja00285a015FARMUG 1152625
T
Fe3Cp3(CO)3(NO)
Chinese Journal of Chemistry (1994) 12, 123YODRAK 1304488 with added H
Co3Cp3(CO)3 doi.org/10.1021/ic00103a003YEWSAU 1302015
Co3Cp3(NO)2 doi.org/10.1021/om00131a028DOHLOB 1143597
Mn3Cp3(NO)4 doi.org/10.1021/ic50135a005TCPMNN10 1268015
U
V2Cp2(CH2CH2CH2CH2)2
doi.org/10.1002/anie.198609251DUYFIM 1147510
CoCp(CH2CH2CH2CH2)(PPh3) doi.org/10.1039/C39770000811CPBYCO 1130882 with added H
Ru(C6Me6)(CH2CH2CH2CH2)(PPh3) doi.org/10.1039/dt9900000179KEKFOV 1194715
Mo(C7H7)(C6H5)(CO)2 doi.org/10.1039/J19690001110CHCFMO10 1124356
V
ReCp(CH2CH2CH2CH2)(CO)2
doi.org/10.1021/om00120a021CUBGAH 1132108
MoCp2(CH2CH2CH2CH2) doi.org/10.1039/dt9830000967BUMBAM 1116665 with added H
TaCp*(CH2CH2CH2CH2)Cl2 doi.org/10.1021/ic50212a056CMCPTA10 1127565 with added H
RhCp*(CH2CHMeCHMeCH2)(PPh3) doi.org/10.1039/dt9880002983GOKGIW 1169835
W
WCp*(PhCH)(NO)(PMe3)
doi.org/10.1021/ja002457eUDELIY 1277879
WCp2(PhCH) doi.org/10.1021/ja00408a065BATKIQ 1106393 with added H
TaCp2(PhCH)(PhCH2) doi.org/10.1021/ja00480a024CBZYTA 1121585
TaCp*(PhCH)(CH2=CHCH=CH2)(PMe3) doi.org/10.1021/om960023fTEQHOM 1269258
X
WCp(CO)2(CH2CH2CH2PPh2)
doi.org/10.1016/0022-328X(90)80257-ZSEWCEC 1258031
FeCp(CO)(CH2CH2CH2PPh2) doi.org/10.1021/om4010516NIVGAC 963927
RhCp*Br(CH2CH2CH2PMe2) doi.org/10.1021/ja00289a014CUWCEC 1134020
RhCp*(CH3CN)(CH2CH2CH2PiPr2)BPh4 doi.org/10.1021/acs.organomet.5b00665WURBOC 1414277
Y
Co3Cp3(PhC)2
doi.org/10.1016/j.ica.2003.08.010AQIXAZ 201481
Ru3Cp3(PhC)(CO)3 doi.org/10.1021/om00041a015PADNEN 1226920
Fe3Cp(CH3C)(CO)8 doi.org/10.1039/dt9830001357BADLUN10 1104851
Ru2Cp2(CO)4(C≡C) doi.org/10.1021/om501270uJIMCIR01 1028932
Z
Ru4(C6H6)(C6H8)(CO)9
doi.org/10.1039/dt9950001555BNCHRU01 1112667 without disorder
MnCp(PMe3)(NO)2CoCp doi.org/10.1021/ja00336a027CUCGAI 1132202
Mn(CO)5(PhCO)Cr(CO)3 doi.org/10.1021/om00038a021VOVTEF 1286716
[VCp*2Br(NO)][VCp*Br2(NO)]doi.org/10.1021/om00125a001DAWBIM 1136787
ZZ
Ru3(C≡C)Cp3(CO)6(BF4)
doi.org/10.1039/b110930hMUBKAV 175273
TiCp2(C5H4C≡CC5H4)Fe2Cp2 doi.org/10.1002/anie.201105248 UDECAJ 826351
Fe2Cp2(CO)3(CH2) doi.org/10.1107/S010827019101123XBEBSAC01 1107509
Fe(C5H4PPh2)2Pt(CH3)4 doi.org/10.1002/ejic.200900454LUDCUJ 731082
Cp = η5-C5H5, Cp* = η5-C5(CH3)5, py = C5H5N, Ph = -C6H5, Cy = -C6H11,
Me = -CH3, Et = -CH2CH3, iPr = -CH(CH3)2, tBu = -C(CH3)3

This page created by George Lisensky, Beloit College. Last modified March 1, 2023.

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