Counter ions might be included. Small deviations from ideal geometry may be due to crystal packing. See original references for the crystal structure.

Metal Carbon ComplexesDOICCDC code
A
Fe(CN)5(NO)-2 		doi.org/10.1107/S2052520614017338AHOLIS 1016354
Fe(CN)5(CO)-3 doi.org/10.1021/ja016434rQUTNIC 176475
Fe(CN)5py-3 doi.org/10.1021/ja0571951SEDQIC 600081
W(CN)5(CO)2-3 doi.org/10.1002/anie.200804199DOPJAU 672442
B
OsPh2(CO)4 		doi.org/10.1021/ic100994tNADQUG 792892
Co(en)(CN)4PPh4 doi.org/10.1002/ejic.201402190BODQES 989258
RhPh(PMe3)3 doi.org/10.1021/ic00269a043FUBKOC 1160356
RhPh(PPh3)2I2 doi.org/10.1021/ja049844zEVEKOF 234538
C
AuMe4– 		doi.org/10.1021/om990043sWEMGUQ 1291939
AuPh4NBu4 doi.org/10.1016/0022-328X(85)80295-3DEYBUE 1139691 with added H
Au(CN)4NBu4 doi.org/10.5517/ccx12ffOTEVUF 835184
Ni(CN)4-2 doi.org/10.1021/ic026101aFUSSIX 142353
Pd(CN)4-2 doi.org/10.1039/C5NJ00071HBOWLIK 764558
Pt(CN)4-2 doi.org/10.1246/cl.2008.398NIXWEX 675670
D
Pd(CN)3Ph-2 		doi.org/10.1021/ja066931dHEXQOR 638702
Pd(CN)3H-2 doi.org/10.1021/ja078298hMOCDOY 692131
cis-Fe(CN)4(CO)2-2 doi.org/10.1021/ic015604yCADYIQ 179155
trans-Fe(CN)4(CO)2-2 doi.org/10.1016/j.synthmet.2004.01.008SEDQIC 226838
CrPh3(C4H8O)3 doi.org/10.1021/acs.organomet.2c00072XEHHAX 2149972
E
Fe(CN)2(CO)3-2 		doi.org/10.1021/ic034455bOKEXEH 206682
Co(CN)2(CO)3– doi.org/10.1039/C3CC43269FYICTUB 927721
Pt(CN)4(NH3)2 Koordinatsionnaia khimiia (1989) 15, 974JIJNIZ 1186325
Ru(CN)2(py)4 doi.org/10.1021/ic00118a006ZALGEY 1308761
F
Fe(CN)2(CO)2(PPh3)I– 		doi.org/10.1016/j.ica.2011.01.069TAWLAG 870653
Fe(CN)2(CO)3I– doi.org/10.1021/ic900929uQUBZUJ 747569
Fe(CN)3(CO)3– doi.org/10.1021/ic015604yCADYEM 179154
Ru(CN)3(CO)3– doi.org/10.1021/ic011030lXIHWEQ 171511
Mn(CN)3(CO)3-2 doi.org/10.1021/ic011030lXIHWAM 163659
Re(CN)3(CO)3-2 doi.org/10.1021/ic049774xEBAPED 243982
G
Mn(CN)6-3 		doi.org/10.1107/S0108270100005369WUYFIH 1431667
Pt(CN)6-2 doi.org/10.1246/cl.2008.398NIXWEX 675670
Fe(CN)6-4 doi.org/10.1039/D0DT04019CXUNNAX03 1937746
Ru(CN)6-4 doi.org/10.1039/D0DT04019CUMENAE 1936975
Os(CN)6-4 doi.org/10.1039/D0DT04019CUMENIM 1946447
Co(CN)6-3 doi.org/10.1039/D0DT04019CEPUXAQ01 1946765
Rh(CN)6-3 doi.org/10.1039/D0DT04019CUMENOS 1946759
Ir(CN)6-3 doi.org/10.1039/D0DT04019CUMEMOR 1935826
H
PdPh(PMe3)2F 		Angewandte Chemie, International Edition
(2002) 41, 4476		VACGUC01 191231
PdPh(AsPh3)2I doi.org/10.1002/hlca.200790083DIDFIG 618851
PdPhCl(bipy) doi.org/10.1016/S0277-5387(98)00404-5HOTLOR 102990
NiPhI(bipy) doi.org/10.1002/anie.201706719CEKJIO 1567350
PdPhMe(bipy) Recueil des Travaux Chimiques des Pays-Bas
(1991) 110, 477		JUDLOJ 1190138
cis-Co(en)2(CN)2+ doi.org/10.1246/bcsj.44.2721CDEDMC10 1121693 with added H
trans-Co(en)2(CN)2+ doi.org/10.1107/S0108270187092497CEHYAP01 1122572
I
Cu(CF3)3(bipy) 		doi.org/10.1002/anie.201411348WOZKUT 1035403
Cu(CN)(PPh3)(bipy) doi.org/10.1080/00958970410001683009AWEMAQ 216300
cis-Fe(CN)2(bipy)2 doi.org/10.14102/j.cnki.0254-5861.2011-2666DACLOM 1918571
cis-Co(CN)2(bipy)2+ doi.org/10.1016/j.poly.2010.08.032ANEGIK 755774
J
W(CN)8-4 		doi.org/10.1016/j.ica.2008.03.001AGADES 673225
Mo(CN)8-4 doi.org/10.1002/anie.201914527SUJJEP 1914245
Os(CN)7-3 doi.org/10.3390/cryst6090102FASLIX 1020688
Mo(CN)7-5 doi.org/10.1021/ic800053eUQAYAO 662665
W(CN)7-3 doi.org/10.1002/anie.201602949EZESIN 1449065
Mo(CN)7-3 doi.org/10.1002/anie.201914527SUJJUF 1915471
K
Ni(CN)Ph(PiPr2CH2CH2PiPr2) 		doi.org/10.1021/om0008474ACEKEY 1100592 with added H
Ni(CN)(CH3)(PiPr2CH2CH2PiPr2) doi.org/10.1021/om049700tDAGLAZ 247367 without disorder
Ni(CN)2(PiPr2CH2CH2PiPr2) doi.org/10.1021/om049700tDAGLED 247368
Fe(CN)H(PPh2CH2CH2PPh2)2 doi.org/10.1016/S0020-1693(03)00249-4EMULUT 207288
L
Ta(CH3)(CO)2(PMe2CH2CH2PMe2)2 		doi.org/10.1021/ic00046a027JULPIP 1190747
Pt(CH3)(py)(PPh2CH2CH2PPh2)CF3SO3 doi.org/10.1021/ic050478+KEBDUR 295422
Ru(CH3)2(PMe2CH2CH2PMe2)2 doi.org/10.1021/om7004063CIMKAL 665447
Pt(CH3)4(PPh2CH2CH2PPh2) doi.org/10.1021/ja029140uBAWPAR 219044
M
Fe(CH2CH2CH2CH2)(PPh3)(CO)3 		doi.org/10.1002/anie.198407111CUBDIM 1132096 with added H
Pd(CH2CH2CH2CH2)(NMe2CH2CH2NMe2) doi.org/10.1071/CH9942119YEMGEC 1301236
Pt(CH2CH2CH2CH2)(PPh3)2 doi.org/10.1021/ic50127a046TPTMPT 1275579
KMn(CH2CH2CH2CH2)2(py) doi.org/10.1002/anie.199003221SEVDAY 1257924
N
Ni(CH2CH2CH2CH2)(bipy) 		doi.org/10.1515/znb-1979-0926DIPNIP 1141475
Pd(CH2CH2CH2CH2)(bipy) doi.org/10.1039/dt9880000133FUNLEF 1161272
Pt(CH2CH2CH2CH2)IPh(bipy) doi.org/10.1021/om040023cNACKOS 245466 without disorder
Co(CH2CH2CH2CH2)(bipy)2ClO4 doi.org/10.1021/acscatal.7b00461XAYWUS 1563194
O
Cr(tBuCH2)4 		doi.org/10.1021/om020237zMUBMIF 183184
Mo(CH3)5 doi.org/10.1039/b000987nDOSBIW 137474
Mo(CH3)6 Angewandte Chemie, International Edition
(2000) 39, 1259		LOJDIX 135548
LiMo(CH3)7 Angewandte Chemie, International Edition
(2000) 39, 1259		LOJDOD 135549 modified H
P
W(CH3)6 		doi.org/10.1126/science.271.5249.626ZOSXEK 1315286
W(CH3)5Cl Chemistry-A European Journal (2001) 7, 3652ACESOQ 156647
W(C6H4(CH2)2)3 doi.org/10.1021/ic500256aJOLWOY 1029667
LiW(CH3)7 doi.org/10.1002/anie.199713501RETNEJ 298719 modified H
Q
Pt2(CH3)8(N2C4H3-C4H3N2) 		doi.org/10.1016/S0020-1693(97)05704-6ROQSAR 1252002
Fe(CH2CH2CH2CH2)(C12N2H8)2 doi.org/10.1021/ic50166a010IBYMPT 1179401
Ni(tBuCH2)2(NMe2CH2CH2NMe2) doi.org/10.1021/acs.organomet.0c00262SUWNEG 1996993
Pt(tBuCH2)2(PEt3)2 doi.org/10.1021/om00061a004BELNUB 1108427
R
Ru(PhCH)Cl2(PCy3)2		doi.org/10.1021/om100185gIKORIK 811503
Os(PhCH)Cl2(CO)(PiPr3)2 doi.org/10.1021/om970139rRUQZAE 1253104
Re(PhCH)(NO)2(PCy3)2+ doi.org/10.1002/chem.200501025
doi.org/10.1039/b604858g		GEGROA 244439
W(PhCH)Cl2(CO)(PMe3)2 doi.org/10.1021/om00145a036FEHJOR 1154110 with added H
S
Cr(Ph2C)(CO)5 		doi.org/10.1002/anie.201308842BISHUI 963597
W(Ph2C)(CO)5 doi.org/10.1021/ja00449a018DPCBWC 1145147
Ir(Ph2C)(PiPr3)2Cl doi.org/10.1021/om020069aIFOMAR 188782
Rh(Ph2C)(PiPr3)2Cl doi.org/10.1002/chem.19970030826NOHKIE 1221817
Ni(Ph2C)(PtBu2CH2CH2PtBu2) doi.org/10.1021/ja0269183MOYZOP 193129
Rh(Ph2C)Cl(PtBu2CH2CH2PtBu2) doi.org/10.1021/om030129sEMOWUY 1149569
T
Cr(PhC)(CO)4Cl 		doi.org/10.1021/ic00075a065CLCBCR06 1127075
Cr(PhC)(CO)4Br doi.org/10.1016/S0022-328X(00)92387-8BRCBCR 1115288 with added H and ring
Co3(PhC)(CO)9 doi.org/10.1107/S0108270186093836UKWOV 1146394
W(PhC)(tBuCH2)3(py) doi.org/10.1016/S0277-5387(00)86763-7JEZBAR 1185585
U
Re(MeC)(PMe3)4ClPF6 		doi.org/10.5517/ccdc.csd.cc29f452NASDOE 2127783
Os(MeC)Cl2H(PiPr3)2 doi.org/10.1021/ic010729oMERYOX 177128
W(tBuC)(tBuCH)(tBuCH2)(PMe2CH2CH2PMe2) doi.org/10.1021/ic50199a025DMPMPW10 1142786
V
W(MeC)(CO)4Br 		doi.org/10.1016/S0022-328X(00)92063-1BMCBCW 1112519 with added H
Cr(MeC)(CO)4Cl doi.org/10.1515/znb-1983-1119CATYOL 1120790
W(PhC)(CO)2(py)2Br doi.org/10.1021/ic00145a005BOXPAF 1114618 with added H
W(PhC)(P(OMe)3)4Cl doi.org/10.5517/ccdc.csd.ccp956bAYEFIV 634421
W
Re(PhC)(PMe3)3Cl2 		doi.org/10.1021/acs.organomet.7b00877CERTOL 1588670
Os(MeC)(PPh3)2Cl3 doi.org/10.1002/ejic.200400003SACREU 227452
W(PhC)H(PiPr2CH2CH2PiPr2)2 doi.org/10.5517/ccdc.csd.ccp5qsbAYEFUH01 631122
Os(PhCOC)(PPh3)2Cl3 doi.org/10.1021/acs.organomet.6b00860FANZIG 1534236
X
Co(CH2CH2CH2PCy2)(CO)3 		doi.org/10.1021/om00141a016FAXYIM 1153207
Mn(CH2CH2CH2PPh2)(CO)4 doi.org/10.1002/cber.19811140713PRPCMN10 1238152 with added H
Ni(CH3)(PiPr2CH2CH2CHCH2CH2PiPr2) doi.org/10.1021/om8005454BOLVAA 631841
RuCl(CO)(PtBu2CH2CH2CHCH2CH2PtBu2) doi.org/10.1021/om0205142QACHAE 1241144
Y
W(PhCO)(CO)5NMe4 		doi.org/10.5517/ccdc.csd.cc2bqw43GECFAZ 2166935.
Pt(PhCO)2(PPh3)2 doi.org/10.1021/om00116a040KEHJOW 1194519
Pt(PhCO)Me(CO)(PPh3) doi.org/10.1021/om00116a040KEHJEM 1194518
Mn(PhCO)(MeCO)(CO)4NMe4 doi.org/10.1021/ja00418a018ACBZMN10 1100500
Z
[Cu(CN)(bipy)2]2[Ni(CN)4] 		doi.org/10.1016/j.poly.2010.09.018ANIFIN 776733
W2(CC6H4C)(CO)8Br2 doi.org/10.1002/cber.19821150903BISFEO 1111594 with added H
Cd2(CN)7-3 doi.org/10.1039/c39930000309SUFGOP 1263731
Pd(PMe3)2(PhCO)Co(CO)4 doi.org/10.1039/dt9950003489POKNAE10 1236384
Cp = η5-C5H5, Cp = η5-C5(CH3)5, py = C5H5N, Ph = -C6H5, Cy = -C6H11, Me = -CH3, Et = -CH2CH3,
iPr = -CH(CH3)2, tBu = -C(CH3)3, en = NH2CH2CH2NH2, bipy =
This page created by George Lisensky, Beloit College. Last modified March 2, 2023.

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