Counter ions are not shown. Small deviations from ideal geometry may be due to crystal packing. See original references for the crystal structure.


Metal-Metal Bond (2)?DOICCDC code
A
Cu2(CH3COO)4(H2O)2		doi.org/10.1039/dt9730002575CUAQAC02 1132069
Cu2(CH3COO)4py2doi.org/10.1107/S0108270188011904PYCUAC02 1240457
Cu2(PhCOO)4(PhCOOH)2doi.org/10.1039/C7DT01571BKUBHOE03 1527825
Cu2Cl4-2doi.org/10.1002/anie.198808561SAKYEI 1254420
B
Pt2(CH3COO)4(H2O)2(ClO4)2		doi.org/10.1021/ja00044a058PAKYUV 1227565
Rh2(CH3COO)+Cp*2H2doi.org/10.1016/S0022-328X(00)93968-8BADHET 1104829
Rh2(CH3COO)4(H2O)2doi.org/10.1107/S0567740871004527ACAQRH10 1100448 with added H
Rh2(CH3COO)4py2doi.org/10.1021/ic50187a046PYACRH 1240387
C
Ru2(CH3COO)4Cl2-2		doi.org/10.1021/ic00260a023ACCRHG01 1100523
Ru2(CH3COO)4Cl2–doi.org/10.1016/j.poly.2004.11.018NALDUA 251382
Os2(CH3COO)4Cl2doi.org/10.1016/S0020-1693(00)81824-1COHNUI 1128841
Tc2(CH3COO)4Cl2doi.org/10.1016/j.poly.2012.09.064CIGHUX 890709
D
Cr2(CH3COO)4(H2O)2		doi.org/10.1021/ic50209a021CRAQAC12 1131603
W2(CF3COO)4(PPh3)2doi.org/10.1021/ic00155a011CAHFIA 1119320
Cr2(CH3COO)4doi.org/10.1021/ja00456a029TACETC 1265080 with added H
Mo2(CH3COO)4doi.org/10.1107/S0567740881008303MOLACE02 1213071
Pt4(CH3COO)8 doi.org/10.1107/S0567740878011632PLATAC01 1235170
E
Re2(CH3COO)2Br4		Zhurnal Neorganicheskoi Khimii (1981) 26, 107ACBRRE10 1100487 with added H
Mo2(CH3COO)2(PPh3)2Cl2 doi.org/10.1016/S0277-5387(00)87246-0GEPDIO 1166054 with added H
Ru2(CH3COO)2(PCy3)2(CO)4 doi.org/10.1002/chem.201003662WAPQUB 798851
Ir2(CH3COO)2(PCy3)2Cl2(CO)2 doi.org/10.1016/S0020-1693(01)00615-6YOFQIT 167648
F
Mo2(CF3COO)2Br4-2		doi.org/10.1021/ic00151a012BURTOX 1117152
Tc2(CH3COO)2Cl4) doi.org/10.1021/ja105730eOSICUP 834033
Ru2(CH3COO)2py(CO)4 doi.org/10.1039/b002304nWONBOQ 149804
Ir2(CH3COO)2py2(CO)3SbF6 doi.org/10.1016/j.ica.2005.01.013YAPCUO 256947
G
Mo2(SO4)4-4		doi.org/10.1021/ic50144a036
Mo2(SO4)4-3doi.org/10.1021/ic50194a051
Mo2(O2P(OPh)2)4doi.org/10.1021/ic00302a047KAFHAA 1192133
Mo2(O2P(OPh)2)4+doi.org/10.1021/ic00091a036LEYCAT 1206348

Other N & P ligands
H
Mo2Cl4(PMe2CH2CH2PMe2)2		doi.org/10.1021/ic00152a017BUTJAB 1117332
Mo2Cl4(pcp)2doi.org/10.1021/ic980972wHEJQOC 114713
W2Cl4(pcp)2doi.org/10.1016/S0020-1693(00)80660-XGADYAL 1162613 with added H
Mo2Br6(pcp)2doi.org/10.1021/ic00011a010JIRVOV 1187034 with added H
W2Cl6(pcp)2doi.org/10.1021/ic00271a017FULSAG 1161080 with added H
Tc2Cl4(pcp)2doi.org/10.1016/S1387-7003(99)00137-9LAQTUS 138939
Re2Cl4(pcp)2doi.org/10.1016/S0020-1693(00)00321-2DECCAP01 1137729
I
W2Cl4H2(pcp)2		doi.org/10.1016/S0277-5387(97)00167-8NOVGIO 1222876
Nb2Cl6(pcp)2doi.org/10.1021/ic00166a031CEGGUQ 1122375 with added H
Re2Cl6(pcp)2doi.org/10.1021/ja00322a024CIDMAD 1124891 with added H
Re2(CO)4(CH2)2(pcp)2doi.org/10.1016/S0022-328X(03)00101-3EJAPEK 200915
J
Re2(CH3)4(pcp)2		doi.org/10.1016/S0022-328X(03)00101-3EJAPAG 200914
Ru2(CO)4(CH2)(pcp)2doi.org/10.1021/om0010417ADEVIO 110125
Ru2(CO)5(pcp)2doi.org/10.1039/a706728cNICVEA 1219575
Ru2(CO)2Cl2(pcp)2doi.org/10.1016/S0022-328X(02)01636-4AGUSIE 187201
K
Ru2(CO)2(CH3CN)4(pcp)2+2		doi.org/10.1021/om990513iQAWLIJ 1241779
Ru2(CO)4I2(pcp)doi.org/10.1039/dt9860000899DOLCEM 1143867 with added H
Ru2Cp*2Cl2(pcp)+2doi.org/10.1007/BF00807583JIZQIS 103549
Ru2Cp2(CO)(CH)(pcp)2+doi.org/10.1039/c39840000841CIFXOE 1125056
L
Pd2(PiPr2CH2PiPr2)2 		doi.org/10.1016/0020-1693(94)03907-0POLWUI 1236552
Rh2(CO)2H2(PiPr2CH2PiPr2)2 doi.org/10.1016/S0022-328X(98)00787-6HIFCUU 102392
Rh2Cp2(CO)(pcp)doi.org/10.1039/dt9840000533BIKWAT10 1110940 with added H
Rh2(CO)2(CH3)(pcp)2+doi.org/10.1016/S0020-1693(00)83821-9LEGHIO 1204869 with added H
M
Co2(CO)6(pcp)		doi.org/10.1021/om050060jJAZFUM 260502
Ir2(CO)2Cl2I2(pcp)2doi.org/10.1016/S0020-1693(00)85149-XWAXDEE 1290754
Ir2Cp*2H2(pcp)+2doi.org/10.1039/b001239oMEFTAS 146419
Ir2(CO)3Cl2(pcp)2doi.org/10.1021/ic00183a023CIXGUL 1126693
N
Ag2(pcp)2+2		doi.org/ 10.1016/j.ica.2004.07.032FOCJUD 241108
Au2(pcp)2+2doi.org/10.1107/S0108270188013630JAMKAJ 1182459
Ni2(CO)3(pcp)2doi.org/10.1021/ja00215a018GEDXAO 1165167 with added H
Pd2Cl2(pcp)2doi.org/10.1016/S0020-1693(01)00682-XMEYTOZ 172851
Pt2(CO)2(pcp)2+2doi.org/10.1021/om00071a002DICPTA10 1140284
O
V2(dpa)4		doi.org/10.1016/S0020-1693(00)00115-8XELTEN 158592
W2(dpa)4+2doi.org/10.1021/ja1114248AVADOR 804045
Mo2(dpa)4doi.org/10.1016/S0020-1693(99)00049-3COXWER 137273
Cr3(dpa)4Cl2doi.org/10.1021/ic990793uNUYZEM01 142841
P
Ru3(dpa)4Cl2		doi.org/10.1016/j.ica.2004.02.041ABUVID 228861
Ni3(dpa)4+3doi.org/10.1021/ja025543i
doi.org/10.1021/ic0262740		FAFVAK 184110
Ni3(dpa)4Cl2doi.org/10.1021/ic0262740UHUROE 209686
Cu3(dpa)4Cl2+doi.org/10.1021/ic0262740UHUSAR 209688
Q
Cr2(pip)4		doi.org/10.1021/ja9912675CAPQAL 133060
Cr2(dmba)4doi.org/10.1021/ic50202a054MBZACR 1210002 with added H
Ru2(dmba)4Cl2doi.org/10.1021/ic0200794IGAJEF 177898
Ru2(dmba)4Ph2doi.org/10.1021/acs.organomet.9b00555QUCQAJ 1947222
R
Co2(dpba)4		doi.org/10.1021/ic00030a018VOZTEJ 1287092
Rh2(dpba)4doi.org/10.1021/ic00030a018VOZTIN 1287094
Pd2(dpba)4doi.org/10.1021/ic00297a013SADLEO 1253778
Au4(dpba)4doi.org/10.1007/s10876-007-0119-8CINFOV 640082
S
Cr2(dmfa)4		doi.org/10.1039/c1cc10194cEPUSAK 808207
Ni2(dmfa)4doi.org/10.1071/CH14271QOMKEK 1006738
Mo2(bipba)2doi.org/10.1021/ja905035fWULRUR 732120
Re2(dpaa)2Cl4doi.org/10.1021/ic50210a037CLAREA 1126996 with added H
T
Cr2(tipmap)2		doi.org/10.1002/anie.200801160HOGKOE 677809
Cr2(dmsfa)2doi.org/10.1002/anie.200803859XOPFEO 694479
Fe2(bippc)2doi.org/10.1002/anie.201203711YEKLIL 2869249
Ni2(bippg)2doi.org/10.1002/chem.201002388INUYUM 789515
U
Cr2(hhpp)4		doi.org/10.1016/S0277-5387(97)00210-6POKMEH 1236376
Mo2(hhpp)4doi.org/10.1016/S0277-5387(97)00210-6POKQAH 1236394
Re2(hhpp)4Cl2doi.org/10.1039/a904684dQAQJOH 1241588
Re2(hhpp)4F2doi.org/10.1021/ic062319bNICREX 644191
V2(hhpp)4doi.org/10.1016/S0277-5387(97)00210-6POKLOQ 1236370
Cu2(hhpp)2doi.org/10.1021/ic980137ePIMXAK 1233988
V
Re2(hhpp)4Cl2+		doi.org/10.1039/b301360jGABPUV 200385
Re2(hhpp)4+2doi.org/10.1021/ic062319bNICQUM 644189
Pd2(hhpp)4doi.org/10.1021/ja9832313JEFHIL 1184024
Pd2(hhpp)4Cl2doi.org/10.1021/ja9832313JEFHOR 114124
W
Cu2(btp)2(CO)2		doi.org/10.1039/C9DT00486FCOCZOM 1895213
Cu2(btp)3(CO)2–doi.org/10.1039/C9DT00486FCOCYIF 1894967
Cu4(btp)4(CO)4Br–doi.org/10.1039/C9DT00486FCOCYEB B1894966
Ru2(btp)2(CO)6doi.org/10.1002/cvde.200306242OJUPAK 197693.
X
Rh2(btp)4(H2O)2		doi.org/10.1039/c1dt11649eRAPBAN 840523
Rh2(btp)2(CH2=CH2)4doi.org/10.1039/c2dt12450eCASVAV 858611
Rh2(bmp)4(CH3CN)2doi.org/10.1016/S0277-5387(00)84092-9GIJCOR 1167827
Ru2(bmp)(CH3COO)(CO)4(PPh3)2doi.org/10.1021/om9600708TOLYIC 1273773
Cp = η5-C5H5, Cp* = η5-C5(CH3)5, Ph = -C6H5, Cy = -C6H11,
Me = -CH3, Et = -CH2CH3, iPr = -CH(CH3)2, tBu = -C(CH3)3,
py = C5H5N

Ligand abbreviations
   pcp = PPh2CH2PPh2,
  dpa = 2,2'-dipyridylamido,
  pip = 2-(phenylimino)piperidinato,
  dmba = dimethylbenzamidinato,
  dpba = diphenylbenzamidinato,
  dmfa = dimethylformamidinato,
  dpaa = diphenylacetamidinato,
  dmsfa = dimesitylformamidinato,
  bipba = bis(2,6-di-isopropylphenyl)benzamidinato,
  bippc = bis(2,6-di-isopropylphenyl)-2,6-dimethylpiperidine-1-carboximidamidato,
  bippg = bis(2,6-di-isopropylphenyl)-1,1-di-isopropylguanidinato,
  tipmap = 2,4,6-tri-isopropylphenylmesitylaminopyridinato,
  hhpp = 1,3,4,6,7,8-hexahydro-2H-pyrimido(1,2-a)pyrimidine,
  btp = 3,5-bis(trifluoromethyl)pyrazolato,
  bmp = 3,5-bis(methyl)pyrazolato


This page created by George Lisensky, Beloit College. Last modified January 31, 2023.

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