_space_group_crystal_system      triclinic
_space_group_name_H-M_alt        'P -1'

_cell_length_a                   12.2528(12)
_cell_length_b                   12.6432(12)
_cell_length_c                   13.4864(13)
_cell_angle_alpha                86.537(2)
_cell_angle_beta                 70.497(2)
_cell_angle_gamma                69.713(2)
_cell_volume                     1843.6(3)
_cell_formula_units_Z            2

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a

_refine_ls_number_reflns         8058
_refine_ls_number_parameters     496
_refine_ls_R_factor_all          0.0557
_refine_ls_R_factor_gt           0.0414

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.58082(2) 0.70321(2) 0.63258(2) 0.01622(8) Uani 1 1 d . . . . .
N1 N 0.5055(2) 0.8434(2) 0.7336(2) 0.0197(5) Uani 1 1 d . . . . .
N2 N 0.4524(2) 0.7113(2) 0.8544(2) 0.0236(6) Uani 1 1 d . . . . .
N3 N 0.5125(2) 0.6398(2) 0.76949(19) 0.0189(5) Uani 1 1 d . . . . .
N4 N 0.6500(2) 0.4558(2) 0.5926(2) 0.0221(6) Uani 1 1 d . . . . .
N5 N 0.6457(2) 0.5512(2) 0.55293(19) 0.0185(5) Uani 1 1 d . . . . .
N6 N 0.4214(2) 0.7570(2) 0.59756(19) 0.0192(5) Uani 1 1 d . . . . .
N7 N 0.5383(2) 0.8441(2) 0.4646(2) 0.0218(5) Uani 1 1 d . . . . .
N8 N 0.6270(2) 0.7876(2) 0.50425(19) 0.0192(5) Uani 1 1 d . . . . .
N9 N 0.8413(2) 0.6857(2) 0.5868(2) 0.0223(6) Uani 1 1 d . . . . .
N10 N 0.7484(2) 0.6648(2) 0.64873(19) 0.0190(5) Uani 1 1 d . . . . .
C1 C 0.5007(3) 0.9501(3) 0.7134(3) 0.0233(7) Uani 1 1 d . . . . .
H1A H 0.5362 0.9667 0.6446 0.028 Uiso 1 1 calc R U . . .
C2 C 0.4447(3) 1.0357(3) 0.7921(3) 0.0283(7) Uani 1 1 d . . . . .
H2A H 0.4424 1.1090 0.7764 0.034 Uiso 1 1 calc R U . . .
C3 C 0.3920(3) 1.0112(3) 0.8947(3) 0.0330(8) Uani 1 1 d . . . . .
H3A H 0.3563 1.0675 0.9488 0.040 Uiso 1 1 calc R U . . .
C4 C 0.3927(3) 0.9031(3) 0.9164(3) 0.0300(8) Uani 1 1 d . . . . .
H4 H 0.3554 0.8863 0.9847 0.036 Uiso 1 1 calc R U . . .
C5 C 0.4502(3) 0.8187(3) 0.8341(2) 0.0230(7) Uani 1 1 d . . . . .
C6 C 0.5258(3) 0.5287(3) 0.7840(2) 0.0203(6) Uani 1 1 d . . . . .
C7 C 0.4755(3) 0.4927(3) 0.8849(2) 0.0252(7) Uani 1 1 d . . . . .
H7 H 0.4247 0.5463 0.9404 0.030 Uiso 1 1 calc R U . . .
C8 C 0.5003(3) 0.3801(3) 0.9024(3) 0.0301(8) Uani 1 1 d . . . . .
H8 H 0.4682 0.3586 0.9700 0.036 Uiso 1 1 calc R U . . .
C9 C 0.5725(3) 0.2975(3) 0.8207(3) 0.0316(8) Uani 1 1 d . . . . .
H9 H 0.5898 0.2214 0.8338 0.038 Uiso 1 1 calc R U . . .
C10 C 0.6182(3) 0.3293(3) 0.7208(3) 0.0286(7) Uani 1 1 d . . . . .
H10 H 0.6645 0.2740 0.6660 0.034 Uiso 1 1 calc R U . . .
C11 C 0.5963(3) 0.4447(3) 0.6989(2) 0.0228(7) Uani 1 1 d . . . . .
C12 C 0.7108(3) 0.5368(2) 0.4402(2) 0.0187(6) Uani 1 1 d . . . . .
C17 C 0.8360(3) 0.4748(3) 0.4024(3) 0.0263(7) Uani 1 1 d . . . . .
H17 H 0.8785 0.4437 0.4489 0.032 Uiso 1 1 calc R U . . .
C16 C 0.8976(3) 0.4596(3) 0.2943(3) 0.0328(8) Uani 1 1 d . . . . .
H16 H 0.9814 0.4174 0.2681 0.039 Uiso 1 1 calc R U . . .
C15 C 0.8345(3) 0.5070(3) 0.2260(3) 0.0340(8) Uani 1 1 d . . . . .
H15 H 0.8760 0.4974 0.1537 0.041 Uiso 1 1 calc R U . . .
C14 C 0.7095(3) 0.5688(3) 0.2645(3) 0.0351(8) Uani 1 1 d . . . . .
H14 H 0.6674 0.6004 0.2178 0.042 Uiso 1 1 calc R U . . .
C13 C 0.6464(3) 0.5839(3) 0.3725(3) 0.0275(7) Uani 1 1 d . . . . .
H13 H 0.5623 0.6252 0.3985 0.033 Uiso 1 1 calc R U . . .
C22 C 0.4296(3) 0.8267(3) 0.5162(2) 0.0206(6) Uani 1 1 d . . . . .
C21 C 0.3265(3) 0.8802(3) 0.4841(3) 0.0248(7) Uani 1 1 d . . . . .
H21 H 0.3321 0.9267 0.4278 0.030 Uiso 1 1 calc R U . . .
C20 C 0.2173(3) 0.8632(3) 0.5371(3) 0.0272(7) Uani 1 1 d . . . . .
H20 H 0.1478 0.8996 0.5179 0.033 Uiso 1 1 calc R U . . .
C19 C 0.2111(3) 0.7914(3) 0.6192(3) 0.0262(7) Uani 1 1 d . . . . .
H19 H 0.1380 0.7783 0.6547 0.031 Uiso 1 1 calc R U . . .
C18 C 0.3144(3) 0.7399(3) 0.6474(3) 0.0242(7) Uani 1 1 d . . . . .
H18 H 0.3102 0.6919 0.7025 0.029 Uiso 1 1 calc R U . . .
C23 C 0.7417(3) 0.7974(3) 0.4568(2) 0.0201(6) Uani 1 1 d . . . . .
C28 C 0.8391(3) 0.7468(3) 0.4988(2) 0.0211(6) Uani 1 1 d . . . . .
C27 C 0.9529(3) 0.7637(3) 0.4490(3) 0.0276(7) Uani 1 1 d . . . . .
H27 H 1.0167 0.7317 0.4763 0.033 Uiso 1 1 calc R U . . .
C26 C 0.9724(3) 0.8252(3) 0.3621(3) 0.0308(8) Uani 1 1 d . . . . .
H26 H 1.0479 0.8353 0.3311 0.037 Uiso 1 1 calc R U . . .
C25 C 0.8774(3) 0.8725(3) 0.3211(3) 0.0304(8) Uani 1 1 d . . . . .
H25 H 0.8902 0.9143 0.2618 0.036 Uiso 1 1 calc R U . . .
C24 C 0.7652(3) 0.8590(3) 0.3660(3) 0.0266(7) Uani 1 1 d . . . . .
H24 H 0.7036 0.8910 0.3363 0.032 Uiso 1 1 calc R U . . .
C29 C 0.7740(3) 0.6057(3) 0.7388(2) 0.0210(6) Uani 1 1 d . . . . .
C30 C 0.7484(3) 0.6684(3) 0.8294(3) 0.0267(7) Uani 1 1 d . . . . .
H30 H 0.7140 0.7468 0.8331 0.032 Uiso 1 1 calc R U . . .
C31 C 0.7747(3) 0.6124(3) 0.9145(3) 0.0351(8) Uani 1 1 d . . . . .
H31 H 0.7591 0.6534 0.9757 0.042 Uiso 1 1 calc R U . . .
C32 C 0.8241(3) 0.4959(4) 0.9092(3) 0.0387(9) Uani 1 1 d . . . . .
H32 H 0.8402 0.4590 0.9673 0.046 Uiso 1 1 calc R U . . .
C33 C 0.8496(4) 0.4343(3) 0.8187(3) 0.0398(9) Uani 1 1 d . . . . .
H33 H 0.8831 0.3558 0.8155 0.048 Uiso 1 1 calc R U . . .
C34 C 0.8253(3) 0.4892(3) 0.7316(3) 0.0304(8) Uani 1 1 d . . . . .
H34 H 0.8433 0.4482 0.6697 0.036 Uiso 1 1 calc R U . . .
P1 P 0.16087(8) 1.04997(8) 1.25877(7) 0.0295(2) Uani 1 1 d . . . . .
F1 F 0.0870(2) 1.1792(2) 1.2480(2) 0.0608(7) Uani 1 1 d . . . . .
F2 F 0.2534(3) 1.0421(3) 1.14357(19) 0.0757(9) Uani 1 1 d . . . . .
F3 F 0.2481(2) 1.0889(2) 1.30236(19) 0.0459(6) Uani 1 1 d . . . . .
F4 F 0.0713(3) 1.0135(2) 1.2167(2) 0.0643(8) Uani 1 1 d . . . . .
F5 F 0.2310(2) 0.9227(2) 1.2761(2) 0.0640(7) Uani 1 1 d . . . . .
F6 F 0.0683(2) 1.0581(2) 1.37576(19) 0.0605(7) Uani 1 1 d . . . . .
C35 C 1.0216(6) 0.1736(7) 0.0309(6) 0.120(3) Uani 1 1 d . . . . .
H35B H 1.0310 0.1908 0.0961 0.144 Uiso 1 1 calc R U . . .
H35A H 1.0643 0.0932 0.0129 0.144 Uiso 1 1 calc R U . . .
Cl1 Cl 0.86435(18) 0.2054(2) 0.05124(16) 0.1210(8) Uani 1 1 d . . . . .
Cl2 Cl 1.08944(12) 0.24672(12) -0.06700(11) 0.0672(3) Uani 1 1 d . . . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Rh1 0.01495(12) 0.01848(12) 0.01378(12) 0.00392(8) -0.00405(9) -0.00527(9)
N1 0.0173(12) 0.0208(13) 0.0195(13) 0.0030(10) -0.0072(10) -0.0040(10)
N2 0.0243(14) 0.0240(14) 0.0146(13) 0.0028(10) -0.0013(11) -0.0043(11)
N3 0.0175(12) 0.0209(13) 0.0154(12) 0.0026(10) -0.0034(10) -0.0056(10)
N4 0.0219(13) 0.0212(13) 0.0221(14) 0.0045(11) -0.0070(11) -0.0069(11)
N5 0.0162(12) 0.0217(13) 0.0166(13) 0.0035(10) -0.0058(10) -0.0054(10)
N6 0.0179(12) 0.0195(13) 0.0182(13) 0.0034(10) -0.0054(10) -0.0051(10)
N7 0.0223(13) 0.0248(14) 0.0191(13) 0.0074(11) -0.0086(11) -0.0086(11)
N8 0.0203(13) 0.0197(13) 0.0185(13) 0.0053(10) -0.0085(10) -0.0067(10)
N9 0.0191(13) 0.0252(14) 0.0233(14) 0.0037(11) -0.0072(11) -0.0088(11)
N10 0.0192(12) 0.0198(13) 0.0164(12) 0.0008(10) -0.0052(10) -0.0054(10)
C1 0.0224(15) 0.0239(16) 0.0254(17) 0.0062(13) -0.0106(13) -0.0084(13)
C2 0.0305(18) 0.0222(17) 0.0313(18) 0.0024(14) -0.0119(15) -0.0066(14)
C3 0.0354(19) 0.0289(18) 0.0259(18) -0.0062(14) -0.0073(15) -0.0022(15)
C4 0.0334(18) 0.0287(18) 0.0197(16) 0.0019(14) -0.0055(14) -0.0042(15)
C5 0.0199(15) 0.0255(16) 0.0188(15) 0.0030(13) -0.0037(12) -0.0051(13)
C6 0.0188(15) 0.0241(16) 0.0187(15) 0.0040(12) -0.0076(12) -0.0074(12)
C7 0.0271(17) 0.0292(17) 0.0194(16) 0.0059(13) -0.0059(13) -0.0123(14)
C8 0.0350(19) 0.0328(19) 0.0246(17) 0.0124(14) -0.0103(15) -0.0157(15)
C9 0.041(2) 0.0239(17) 0.0325(19) 0.0117(14) -0.0143(16) -0.0146(15)
C10 0.0314(18) 0.0243(17) 0.0286(18) 0.0045(14) -0.0105(15) -0.0078(14)
C11 0.0242(16) 0.0229(16) 0.0212(16) 0.0050(12) -0.0087(13) -0.0077(13)
C12 0.0201(15) 0.0188(15) 0.0170(15) 0.0005(12) -0.0048(12) -0.0079(12)
C17 0.0225(16) 0.0313(18) 0.0236(17) 0.0037(14) -0.0090(13) -0.0067(14)
C16 0.0188(16) 0.043(2) 0.0288(19) 0.0003(16) 0.0003(14) -0.0089(15)
C15 0.037(2) 0.046(2) 0.0177(17) 0.0026(15) -0.0026(15) -0.0188(17)
C14 0.037(2) 0.046(2) 0.0217(17) 0.0024(16) -0.0146(16) -0.0097(17)
C13 0.0251(17) 0.0312(18) 0.0241(17) -0.0033(14) -0.0109(14) -0.0039(14)
C22 0.0209(15) 0.0207(15) 0.0203(15) 0.0021(12) -0.0084(13) -0.0059(12)
C21 0.0270(17) 0.0245(17) 0.0254(17) 0.0052(13) -0.0124(14) -0.0089(13)
C20 0.0184(15) 0.0301(18) 0.0318(18) -0.0005(14) -0.0112(14) -0.0038(13)
C19 0.0207(16) 0.0275(17) 0.0304(18) 0.0034(14) -0.0070(14) -0.0101(13)
C18 0.0210(15) 0.0265(17) 0.0232(16) 0.0018(13) -0.0047(13) -0.0087(13)
C23 0.0211(15) 0.0217(15) 0.0173(15) 0.0003(12) -0.0044(12) -0.0088(12)
C28 0.0205(15) 0.0234(16) 0.0186(15) 0.0010(12) -0.0056(12) -0.0074(12)
C27 0.0200(16) 0.0319(18) 0.0298(18) 0.0018(14) -0.0065(14) -0.0098(14)
C26 0.0239(17) 0.037(2) 0.0288(18) 0.0034(15) 0.0002(14) -0.0165(15)
C25 0.0327(18) 0.036(2) 0.0215(17) 0.0079(14) -0.0033(14) -0.0169(16)
C24 0.0281(17) 0.0309(18) 0.0224(17) 0.0088(14) -0.0095(14) -0.0122(14)
C29 0.0155(14) 0.0284(17) 0.0208(16) 0.0068(13) -0.0084(12) -0.0085(12)
C30 0.0227(16) 0.0326(18) 0.0238(17) 0.0042(14) -0.0072(13) -0.0094(14)
C31 0.0327(19) 0.053(2) 0.0208(17) 0.0047(16) -0.0090(15) -0.0160(17)
C32 0.034(2) 0.055(3) 0.0268(19) 0.0197(17) -0.0143(16) -0.0149(18)
C33 0.042(2) 0.035(2) 0.047(2) 0.0170(18) -0.0262(19) -0.0098(17)
C34 0.0322(18) 0.0314(19) 0.0321(19) 0.0046(15) -0.0186(16) -0.0092(15)
P1 0.0290(5) 0.0280(5) 0.0317(5) 0.0078(4) -0.0118(4) -0.0093(4)
F1 0.0472(14) 0.0377(14) 0.109(2) 0.0256(14) -0.0436(15) -0.0151(11)
F2 0.087(2) 0.103(2) 0.0307(14) -0.0046(14) 0.0050(14) -0.0478(19)
F3 0.0338(12) 0.0533(15) 0.0562(15) 0.0028(11) -0.0210(11) -0.0159(11)
F4 0.096(2) 0.0677(18) 0.0735(18) 0.0334(15) -0.0582(17) -0.0580(17)
F5 0.0598(16) 0.0311(13) 0.091(2) 0.0101(13) -0.0282(15) -0.0022(12)
F6 0.0377(13) 0.088(2) 0.0468(15) 0.0056(14) -0.0007(11) -0.0238(13)
C35 0.084(5) 0.163(8) 0.122(6) 0.093(6) -0.055(4) -0.047(5)
Cl1 0.0888(12) 0.183(2) 0.1117(14) 0.0633(14) -0.0431(11) -0.0716(14)
Cl2 0.0619(8) 0.0744(9) 0.0694(8) 0.0154(7) -0.0357(7) -0.0173(6)